Project information
Chalcogen organic compounds - synthesis, transformation and structure elucidation
- Project Identification
- GA203/01/1333
- Project Period
- 1/2001 - 1/2003
- Investor / Pogramme / Project type
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Czech Science Foundation
- Standard Projects
- MU Faculty or unit
- Faculty of Science
The substantiality of this project is extension of new acknowledgments found by applicant research group in field of syntheses, transformations and structure elucidation of heterocycles containing nitrogen, sulfur, selenium and tellurium into molecule. F irst of all synthesis, transformation reactions and elucidation of bond conditions will be studied on some novel compounds containing trichalcapentalene skeleton. Furthermore studies of formation and reactivity of heterocycles containing S-S, S-Se, S-Te, Se-Se, Se-Te bonds, i. e. potential scavengers of free radicals. Formation of chalcogene-chalcogene bond will be realized by oxidative cyclization on 2-chalcogenoureidothiophenole and 2-chalcogenoureido-ethanthiole as model (chalcogen is S or Se). Along on compounds prepared by addition of chalcogenide anion on both cyano groups into dinitrile diaminomaleic acid and its derivatives with iunctionalized amino group (acyl-, thioacylamino, and chalcogenoureido groups). By an application of electrochemical
Publications
Total number of publications: 34
2003
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Syntheses and Structure Study on 3,3alambda4,4-Trithia-1-azapentalenes and Their 3-Oxa Analogues
Collection of Czechoslovak Chemical Communications, year: 2003, volume: 68, edition: 7
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SYNTHESIS OF A NOVEL 4H-BENZO[1.2.4]DITHIAZINE SYSTEM AND STUDIES OF ITS ELECTROCHEMICAL BEHAVIOUR
Proceedings of ECSOC-7, The Seventh International Electronic Conference on Synthetic Organic Chemistry, http://www.mdpi.org/ecsoc-7.htm, September 1-30, 2003. Editors: Julio A. Seijas, De-Chun Ji and Shu-Kun Lin. CD-ROM edition, year: 2003
2002
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A regioselectivity of electrophilic attacks to 5-amino-3-thioxo-3H-1,2-dithiole-4-carboxylic acid functional derivatives. An elucidation of product structures
Heterocyclic Communications, year: 2002, volume: 2002, edition: 1
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Kinetically and Thermodynamically Controlled Domino-Reaction; Synthesis of Novel 1,3-Oxathioles and 1,3-Thiazoles
9th Blue Danube Symposium on Heterocyclic Chemistry, Book of Abstracts, year: 2002
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Kineticky a termodynamicky kontrolovaný průběh domino reakce - Syntéza nových 1,3-oxathiolů a 1,3-thiazolů
Chemické Listy, year: 2002, volume: 96, edition: 6
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New Domino-Reaction for the Synthesis of N4-(5-Aryl-1,3-oxathiol-2-yliden)-2-phenylquinazolin-4-amines and 4-[4-Aryl-5-(2-phenylquinazolin-4-yl)-1,3-thiazol-2-yl]morpholine
Journal of Heterocyclic Chemistry, year: 2002, volume: 2002, edition: 39
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Nové cesty transformace trithionů jako způsob přípravy heteropentalenů
Chemické Listy, year: 2002, volume: 96, edition: 6
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Reactivity Study on Morpholine-1-carbothioic acid (2-phenyl-3H-quinazolin-4-ylidene) amide
Journal of Heterocyclic Chemistry, year: 2002, volume: 2002, edition: 39
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SYNTHESIS of 4-AMINO-3-CYANO-2-MORPHOLINOQUINOLINE
Heterocyclic Communications, year: 2002, volume: 2002, edition: 1
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Synthesis of Heterocyclic Skeletons by the Reaction of N1-(2-Cyanophenyl)-benzimidoyl Chloride with Thioamides
Molecules, year: 2002, volume: 96, edition: 1