Project information
Chalcogen organic compounds - synthesis, transformation and structure elucidation
- Project Identification
- GA203/01/1333
- Project Period
- 1/2001 - 1/2003
- Investor / Pogramme / Project type
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Czech Science Foundation
- Standard Projects
- MU Faculty or unit
- Faculty of Science
The substantiality of this project is extension of new acknowledgments found by applicant research group in field of syntheses, transformations and structure elucidation of heterocycles containing nitrogen, sulfur, selenium and tellurium into molecule. F irst of all synthesis, transformation reactions and elucidation of bond conditions will be studied on some novel compounds containing trichalcapentalene skeleton. Furthermore studies of formation and reactivity of heterocycles containing S-S, S-Se, S-Te, Se-Se, Se-Te bonds, i. e. potential scavengers of free radicals. Formation of chalcogene-chalcogene bond will be realized by oxidative cyclization on 2-chalcogenoureidothiophenole and 2-chalcogenoureido-ethanthiole as model (chalcogen is S or Se). Along on compounds prepared by addition of chalcogenide anion on both cyano groups into dinitrile diaminomaleic acid and its derivatives with iunctionalized amino group (acyl-, thioacylamino, and chalcogenoureido groups). By an application of electrochemical
Publications
Total number of publications: 34
2001
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The Reactivity Study on N3,N3-(3-Oxapentan-1,5-diyl)-N1-(2-phenyl-3,4-dihydroquinazolin-4-yliden)thiourea. Part 2: Reaction with Phenacyl Bromides and Chloroacetic Acid Derivatives
Proceedings of ECSOC-5, The Fifth International Electronic Conference on Synthetic Organic Chemistry, http://www.mdpi.org/ecsoc-5.htm, year: 2001
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The Synthesis of New N3-Aryl-N1-(2-phenylquinazolin-4-yl)thioureas
XXVth Conference of Organic Chemists, year: 2001
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Three-component Domino-reaction of Diaminomaleodinitrile
53. zjazd chemických spoločností, year: 2001
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Transformace derivátů 4lambda4-1,2-dithiolo[1,5-b][1,2,4]dithiazolu a 3-(R-karbonylimino)-3H-1,2-dithiolu působením dusíkatých nukleofilů
Sborník príspevkov 53. zjazd Chemických spoločností, year: 2001